Octahedral to trigonal prismatic distortion driven by subjacent orbital π antibonding interactions and modulated by ligand redox noninnocence.
نویسندگان
چکیده
Ru(ONO)2 and Os(ONO)2 distort from octahedral towards trigonal prismatic geometry in order to relieve π antibonding due to donation from the second-highest ligand orbital to the metal. Increasing oxidation of the ONO ligand suppresses distortion by increasing σ* interactions in the trigonal prism.
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عنوان ژورنال:
- Chemical communications
دوره 50 59 شماره
صفحات -
تاریخ انتشار 2014